Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption.
نویسندگان
چکیده
The synthesis and successful activation of IRMOF-8 (Zn(4)O(ndc)(3), ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO(2) yields a guest-free material with a BET surface area of 4461 m(2) g(-1).
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 79 شماره
صفحات -
تاریخ انتشار 2012